| 棣栭〉 | 璧勮涓績(jī) | 鍖栧伐鍟嗚錘 | 縐戝鐮旂┒ | 浜т笟鍙戝睍 | 浜烘墠浜ゆ祦 | 浼?xì)灞曚俊鎭?/a> | 瀹炵敤緗戝潃 | 緹よ嫳鑱氶 | 瀛﹁呬粙緇?/a> | 浼?xì)鍛樹腑蹇?jī) | 璁哄潧 | ||
 | 濉戞枡 | 姍¤兌 | 綰ょ淮 | 娑傛枡涓庢補(bǔ)澧?/a> | 鑳剁矘鍓?/a> | 澶嶅悎鏉愭枡 | 鐭沖寲 | 鍖栧伐 | 浠櫒浠〃 | 鏂頒駭涓?/a> | 涓撻 | 榪斿洖棣栭〉 |
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| 棣栭〉 | 璧勮涓績(jī) | 鍖栧伐鍟嗚錘 | 縐戝鐮旂┒ | 浜т笟鍙戝睍 | 浜烘墠浜ゆ祦 | 浼?xì)灞曚俊鎭?/a> | 瀹炵敤緗戝潃 | 緹よ嫳鑱氶 | 瀛﹁呬粙緇?/a> | 浼?xì)鍛樹腑蹇?jī) | 璁哄潧 | ||
| 濉戞枡 | 姍¤兌 | 綰ょ淮 | 娑傛枡涓庢補(bǔ)澧?/a> | 鑳剁矘鍓?/a> | 澶嶅悎鏉愭枡 | 鐭沖寲 | 鍖栧伐 | 浠櫒浠〃 | 鏂頒駭涓?/a> | 涓撻 | 榪斿洖棣栭〉 |
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鐐斿熀鍨嬫湁鏈哄寲鍚堢墿鍦ㄥ寲瀛︺佺敓鐗╁拰鏉愭枡棰嗗煙鍧囨湁閲嶈鐨勫簲鐢ㄤ環(huán)鍊箋傜劧鑰岋紝鐢變簬鐐旂儍浼楀鐨勫弽搴旇礬寰勶紝鐐旂儍澶氳仛鐗╃殑閫夋嫨鎬у悎鎴愪竴鐩翠互鏉ユ槸鍖栧鐣岄潰涓寸殑閲嶅ぇ闅鵑涔嬩竴銆備紶緇熺殑婧舵恫鍙嶅簲涓鑸渶瑕侀氳繃澶嶆潅鐨勫弽搴旂墿鍜屽偓鍖栧墏鏉ュ埗澶囩倲鐑冨鑱氱墿錛屼絾鏄駭鐜囦緷鐒朵笉鐢氱悊鎯熾傝繎鏈燂紝涓浗縐戝鎶鏈ぇ瀛﹀浗瀹跺悓姝ヨ緪灝勫疄楠屽鏁欐巿鏈變繆鍙戣棰樼粍涓庡寲瀛︿笌鏉愭枡縐戝瀛﹂櫌鏁欐巿姝︽檽鍚涜棰樼粍鍚堜綔錛屽彂灞曚簡(jiǎn)涓縐嶅叏鏂扮殑鐐旂儍鍖栧悎鐗╃殑琛ㄩ潰闄愬煙鍚堟垚娉曪紝鎴愬姛鍦板湪Ag(111)鍗曟櫠琛ㄩ潰鍚堟垚鍑轟駭鐜囬珮杈?0%鐨勯『寮忕儻浜岀倲鍨嬪寲鍚堢墿錛屽茍緇撳悎涓緋誨垪鎺у埗瀵規(guī)瘮瀹為獙鍜屽瘑搴︽硾鍑界悊璁鴻綆楋紝鎻ず浜?jiǎn)璋冩帶璇ュ弽搴旂殑鏈虹悊銆傜浉鍏崇爺絀惰鏂囧彂琛ㄤ簬鍥介檯鏈熷垔銆婂痙鍥藉簲鐢ㄥ寲瀛︺嬶紙Angew. Chem. Int. Ed.錛?017, DOI: 10.1002/anie.201701142)錛屽崥澹敓鐜嬫稕涓鴻鏂囩涓浣滆呫?
鐮旂┒鑰呭埄鐢ㄦ捍鍙栦唬鐨勪箼鐐旇仈鑻綔涓哄墠椹變綋鍒嗗瓙錛屽湪鐑捀鍙戝埌420 K鐨凙g(111)琛ㄩ潰涔嬪悗錛屽艦鎴愪簡(jiǎn)澶ч潰縐湁搴忕殑欏哄紡鐑簩鐐斿矝灞匡紝欏哄紡鐑簩鐐斾駭鐜囪揪鍒?0%銆傝繖鏄洜涓鴻娓╁害涓婥-Br閿柇瑁傦紝琛ㄩ潰鍚擱檮鐨凚r鍘熷瓙閫氳繃婧存阿鍗ら敭鐨勪綔鐢ㄤ嬌鐢熸垚鐨勯『寮忕儻浜岀倲鑱氶泦鎴愭湁搴忕殑瀵嗗爢宀涘笨錛屽瘑鍫嗗矝灞塊犳垚鐨勭┖闂翠綅闃婚樆紕嶄簡(jiǎn)欏哄紡鐑簩鐐旂殑榪涗竴姝ュ弽搴旓紝瀵艱嚧浜?jiǎn)鍏堕珮閫夋嫨鎬с傚姣斿疄楠岃瘉鏄庝簡(jiǎn)鍦ㄦ病鏈夋捍鍙栦唬鍩虹殑鎯呭喌涓嬶紝涔欑倲鑱旇嫰鐢熸垚鐨勪駭鐗╁茍涓嶅叿澶囦換涓鐗╃鐨勯珮閫夋嫨鎬с傜悊璁鴻綆楀悓鏍烽獙璇佷簡(jiǎn)榪欑鑱氶泦鏁堝簲鍙互鏋佸ぇ鍦版彁楂橀『寮忕儻浜岀倲鐨勮繘涓姝ュ弽搴旇兘鍨掋?
鏈變繆鍙戣棰樼粍闄や簡(jiǎn)鑷村姏浜庡悓姝ヨ緪灝勬柟娉曞強(qiáng)搴旂敤鏂歸潰鐨勭爺絀朵互澶栵紝榪戝勾鏉ュ湪鍒╃敤琛ㄩ潰闄愬煙鎵嬫璋冩帶鏈夋満鍒嗗瓙鍙?qiáng)鑱氬悎鐗╁湪琛ㄩ潰鐨勫悎鎴愬拰鏈虹悊鐮斀I舵柟闈篃鍙栧緱浜?jiǎn)涓浜涜繘灞曪紝濡傚埄鐢ㄤ箤灝?dāng)鏇煎弽搴斿湪Cu(111)琛ㄩ潰鍚堟垚瓚呰嫰鍒嗗瓙錛圓ngew. Chem. Int. Ed. 2013, 52, 4668錛汚CS Nano 2014, 8, 709錛夊強(qiáng)鍒╃敤Cu (110)-(2×1) O瓚呮爡鏍艱〃闈㈠埗澶囩壒瀹氬搴︾殑鏈夋満綰崇背緇撴瀯錛圓CS Nano 2016, 10, 3747錛夌瓑銆?
涓婅堪鐮旂┒宸ヤ綔寰楀埌浜?jiǎn)鍥藉畨檱嶇偣鍩杭媭鐮旂┒鍙戝睍璁″垝(鈥?73鈥濊鍒?銆佸浗瀹惰嚜鐒剁瀛﹀熀閲戝拰涓浗縐戝闄㈠悎鑲ュぇ縐戝涓績(jī)鍩洪噾絳夐」鐩殑璧勫姪銆?