娓腑澶э紙娣卞湷錛夋湵涓栧鉤鍜屽紶紲哄洟闃燂細(xì)楂樻媺浼搞侀珮閫忔槑鐨勫叏鍥烘佹湰寰佸鐢?shù)寮规?/span>
2021-07-16 鏉ユ簮:涓浗鑱氬悎鐗╃綉 鐐瑰嚮嬈?/span>
鍏抽敭璇嶏細(xì)鏌旀у彲鎷変幾鐢?shù)瀛愬櫒錃g
鏌旀у彲鎷変幾鐢?shù)瀛愬櫒錃g榪戝勾鏉ョ殑椋為熷彂灞曚績(jī)榪涗簡(jiǎn)鍙媺浼稿鐢墊潗鏂欑殑騫挎硾鐮旂┒銆傚叾涓紝瀵肩數(shù)寮規(guī)т綋鐢變簬鍏跺嚭鑹茬殑鎷変幾鎬ц兘銆佷紭瓚婄殑閫忔槑鎬у拰鍏ㄥ浐鎬佺壒鎬х瓑浼樼偣鑰屽鍙楀叧娉ㄣ傚鐢?shù)寮规т綋鍙互鐢ㄦ潵鍒朵綔鏌旀у彲鎷変幾鍣ㄤ歡錛堝寘鎷紶鎰熷櫒銆侀┍鍔ㄥ櫒銆佺數(shù)緙嗙瓑錛夊強(qiáng)鍏剁粍浠訛紙濡傜數(shù)鏋併佺數(shù)綰跨瓑錛夈傚綋鍓嶏紝瀵肩數(shù)寮規(guī)т綋鐨勫埗澶囦富瑕佹槸鍩轟簬灝嗗鐢?shù)濉枡澶嶅悎鍒板家?guī)т綋鍩轟綋涓紝鍏稿瀷鐨勫～鏂欏寘鎷浐鎬佸鐢?shù)濉枡锛堝閲戝睘銆佺⒊銆佸鐢?shù)楂樺垎瀛惤{夛級(jí)鍜屾恫鎬佸鐢?shù)濉枡锛堝娑叉侀噾灞炪佹恫鎬佺數(shù)瑙ｈ川絳夛級(jí)銆傜劧鑰岋紝鍥烘佸鐢?shù)濉枡涓嶅彲閬垮厤鐨勭壓鐗蹭簡(jiǎn)寮规т綋鐨勬媺浼告ц兘鍜岄忔槑鎬ц兘錛岃屾恫鎬佸鐢?shù)濉枡鐨勫鍚堟栆?guī)硶澶嶆潅銆佸瓨鍦ㄦ硠婕忛闄╃瓑闂闄愬埗浜?jiǎn)鍏跺簲鐢ㄥ満鏅傚洜姝わ紝寮鍙戝吋欏炬媺浼稿拰閫忔槑鎬ц兘涓旀柟渚垮埗澶囩殑瀵肩數(shù)寮規(guī)т綋鏉愭枡鍙瀬澶у湴鎷撳鍏跺簲鐢ㄩ鍩燂紝浣嗙洰鍓嶄粛鏈夎緝澶ф寫鎴樸?/span>
閴翠簬姝わ紝棣欐腐涓枃澶у錛堟繁鍦籌級(jí)鏈變笘騫沖拰寮犵ズ鍥㈤槦鎻愬嚭涓縐嶅埗澶囩畝鍗曠殑鏈緛瀵肩數(shù)寮規(guī)т綋錛堢瀛愬脊鎬т綋錛?/span>鏉ュ疄鐜板吋欏炬媺浼稿拰閫忔槑鎬ц兘鐨勭洰鐨勩傝鐮旂┒鎴愭灉浠?/span>鈥?/span>Highly Transparent, Stretchable, and Conducting Ionoelastomers Based on Poly(ionic liquid)s鈥?/span>榪戞湡鍙戣〃鍦?/span>ACS Applied Materials & Interfaces錛坉oi: 10.1021/acsami.1c05833錛夛紝棣欐腐涓枃澶у錛堟繁鍦籌級(jí)鐞嗗伐瀛﹂櫌鏄庡皬搴?/span>鍗氬＋涓鴻鏂囩涓浣滆咃紝閫氳浣滆呬負(fù)棣欐腐涓枃澶у錛堟繁鍦籌級(jí)鐞嗗伐瀛﹂櫌鏈變笘騫?/span>鏁欐巿鍜屽姪鐞嗘暀鎺?/span>寮犵ズ鍗氬＋銆?br />
鍥?span style="font-family:;">1
. 鏈緛瀵肩數(shù)寮規(guī)т綋錛堢瀛愬脊鎬т綋錛夌殑璁捐銆?span style="font-family:;">(a) 紱誨瓙浠ュ叡浠烽敭閾炬帴鍒板脊鎬т綋鍩轟綋涓婏紝鑰屽弽紱誨瓙錛?span style="font-family:;">[TFSI]錛変綔涓鴻縼縐葷數(shù)鑽峰艦鎴愬鐢?shù)閫氳礬銆傦紙b錛夌瀛愬脊鎬т綋鐨勯珮鎷変幾銆侀珮閫忔槑鐓х墖銆傦紙c錛夌瀛愬脊鎬т綋鍦?/span>400?800 nm鑼冨洿鐨勯忓厜鐜囥傦紙d錛夌瀛愮數(shù)瀵肩巼闅忔俯搴︾殑鍙樺寲鏇茬嚎銆?/span>
鍥?/span>2.紱誨瓙寮規(guī)т綋鐨勭數(shù)瀛︽ц兘鍜屾満姊版ц兘鐨勮皟鎺с?/span>涓嶅悓棰戠巼涓嬬殑錛?span style="font-family:;">a錛夐樆鎶楁ā鍊煎拰錛?/span>b錛夎礋鐩鎬綅瑙掋傦紙c錛?span style="font-family:;">Nyquist 鏇茬嚎銆傦紙d錛夊簲鍔?span style="font-family:;">-搴斿彉鏇茬嚎銆傦紙e錛変笉鍚屽簲鍙樹笅鐨勬媺浼?span style="font-family:;">-鍥炲鏇茬嚎銆傦紙f錛夌粍鎴愬紱誨瓙鐢?shù)瀵肩巼鍜屾潹姘忔ā閲忕殑濯?jiǎng)鍝嶃?/span>
鍥?/span>3.紱誨瓙寮規(guī)т綋鐨勭ǔ瀹氭с?/span>錛?span style="font-family:;">a錛?span style="font-family:;">TGA鏇茬嚎銆傦紙b錛?span style="font-family:;">DSC鏇茬嚎銆傦紙
c錛変笉鍚屾俯搴︾殑絀烘皵涓け閲嶆洸綰褲傦紙d錛夐噾灞?span style="font-family:;">-寮規(guī)т綋綺橀檮鍔涙紨紺恒傦紙
e錛夌數(shù)鍖栧紼沖畾紿楀彛嫻嬭瘯銆傦紙
f錛夊簲鍙樺鐢?shù)瀵肩巼鐨勫奖鍝嶃?/span>
鍥?/span>4. 鍩轟簬紱誨瓙寮規(guī)т綋鐨勬按涓嬩紶鎰熷櫒銆?/span> (a) 姘翠笅浼犳劅鍣ㄧ殑緇撴瀯紺烘剰鍥俱?nbsp;(b) 涓嶅悓鎵嬫寚寮洸瑙掑害鐨勭浉瀵歸樆鎶楀彉鍖栫巼銆傦紙c錛夌浉瀵歸樆鎶楀彉鍖栫巼鐨勫搷搴旀潵媯(gè)嫻嬫墜鎸囧集鏇?span style="font-family:;">-閲婃斁鐨勯噸澶嶅姩浣溿?/span>(d) 鐩稿闃繪姉鍙樺寲鐜囧湪涓嶅悓鎵嬫寚鍔ㄤ綔棰戠巼涓嬬殑鍝嶅簲銆?br />
鍥?/span>5. 鍩轟簬紱誨瓙寮規(guī)т綋鐨勯忔槑浠嬬數(shù)寮規(guī)т綋椹卞姩鍣ㄣ?/span>錛?/span>a錛夊拰錛?/span>b錛変粙鐢?shù)寮规т綋椹卞姩鍣ㄥ熀鏈粨鏋勫拰宸ヤ綔鍘熺悊銆傦紙c錛夊熀浜庣瀛愬脊鎬т綋鐨勯┍鍔ㄦ晥鏋溿傦紙d錛夊熀浜庣瀛愬嚌鑳剁殑椹卞姩鏁堟灉銆?/span>
紱誨瓙寮規(guī)т綋鐨勮璁＄瓥鐣ヤ富瑕佹槸灝嗙瀛愪互鍏變環(huán)閿摼鎺ュ埌寮規(guī)т綋鍩轟綋涓婏紝鑰屽弽紱誨瓙浣滀負(fù)榪佺Щ鐢?shù)鑽峰舰鎴愬鐢?shù)閫氳礬銆傚叾涓紝紱誨瓙娑蹭綋鍗曚綋錛圼EIC6A][TFSI]錛夋彁渚涜壇濂界殑紱誨瓙鐢?shù)瀵肩巼锛屼笝鐑呮竵閰紙BA錛夎祴浜堝脊鎬т綋浼樺紓鐨勬媺浼告ц兘錛屼簩鑰呰壇濂界殑鐩稿鎬у垯淇濊瘉浜?jiǎn)鏉愭枡鐨勯珮閫忔槑鎬э紙鍥?錛夈傞氳繃綆鍗曠殑娣峰悎涓ょ鍗曚綋騫朵氦鑱斿浐鍖栵紝渚垮彲寰楀埌鏈緛瀵肩數(shù)寮規(guī)т綋錛屽叾閫忓厜鐜囬珮杈?6%錛屾柇瑁傚簲鍙樺彲杈?460%錛屽娓╃數(shù)瀵肩巼涓?.17 × 10?5 S/cm銆傜敱姝よ璁＄殑紱誨瓙寮規(guī)т綋娌℃湁浠諱綍鍥轟綋鎴栬呮恫浣撳鐢?shù)濉枡鐨勬氛d姞錛屼粠鑰岄伩鍏嶄簡(jiǎn)鍔涘銆侀忓厜鐜囩瓑鐢變簬澶嶅悎瀵艱嚧鐨勬ц兘涓嬮檷錛屼互鍙?qiáng)鏃犳恫浣撴硠婕忔垨鑰呭惛鏀舵箍姘旂殑椋庨櫓銆傛洿閲嶈鐨勬槸錛屼綔涓哄潎鐩鎬綋緋伙紝榪欑鏈緛瀵肩數(shù)寮規(guī)т綋鏈夌潃浼樺紓鐨勭ǔ瀹氭ц兘錛屽寘鎷儹紼沖畾鎬с佺幆澧冪ǔ瀹氭с佺數(shù)鍖栧紼沖畾鎬у拰鐢墊満姊扮ǔ瀹氭с傝紱誨瓙寮規(guī)т綋鍙垚鍔熷湴搴旂敤鍒版按涓嬩紶鎰熷櫒鍜岄忔槑浠嬬數(shù)寮規(guī)т綋椹卞姩鍣ㄤ笂銆?/span>
鐩稿叧閾炬帴
https://pubs.acs.org/doi/full/10.1021/acsami.1c05833
鍏嶈矗澹版槑錛氶儴鍒嗚祫鏂欐潵婧愪簬緗戠粶錛岃漿杞界殑鐩殑鍦ㄤ簬浼犻掓洿澶氫俊鎭強(qiáng)鍒嗕韓錛屽茍涓嶆剰鍛崇潃璧炲悓鍏惰鐐規(guī)垨璇佸疄鍏剁湡瀹炴э紝
涔熶笉鏋勬垚鍏朵粬寤鴻銆備粎鎻愪緵浜ゆ祦騫沖彴錛屼笉涓哄叾鐗堟潈璐熻矗銆傚娑夊強(qiáng)渚墊潈錛岃鑱旂郴鎴戜滑鍙?qiáng)鏃朵慨鏀规垨鍒犻櫎銆?br>閭錛歩nfo@polymer.cn
錛堣矗浠葷紪杈戯細(xì)sun錛?
