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 | 濉戞枡 | 姍¤兌 | 綰ょ淮 | 娑傛枡涓庢補(bǔ)澧?/a> | 鑳剁矘鍓?/a> | 澶嶅悎鏉愭枡 | 鐭沖寲 | 鍖栧伐 | 浠櫒浠〃 | 鏂頒駭涓?/a> | 涓撻 | 榪斿洖棣栭〉 |
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| 濉戞枡 | 姍¤兌 | 綰ょ淮 | 娑傛枡涓庢補(bǔ)澧?/a> | 鑳剁矘鍓?/a> | 澶嶅悎鏉愭枡 | 鐭沖寲 | 鍖栧伐 | 浠櫒浠〃 | 鏂頒駭涓?/a> | 涓撻 | 榪斿洖棣栭〉 |
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浣庤〃闈㈣兘鏉愭枡錛岃濡傜壒姘熼緳錛堣仛鍥涙盁涔欑儻錛夋秱灞傦紝浠ュ叾浼樺紓鐨勫寲瀛︽儼鎬у拰鎶楁鼎婀挎ц兘鏉ユ姷鎶楁補(bǔ)姹＄殑闄勭潃銆?/span>鑰岃繖浜涙樉钁楃殑浼樼偣涔熶嬌寰椾紶緇熺殑鑳墮粡鍓?/span>寰堥毦涓庡叾寤虹珛鐞嗘兂鐨勭矘鎺ュ己搴?/span>銆傞殢鐫姝ょ被浣庤〃闈㈣兘鏉愭枡鍦ㄦ苯杞︺佺數(shù)瀛愬拰鍖葷枟琛屼笟鐨勫箍娉涘簲鐢紝鍙戝睍涓庝箣鍖歸厤鐨?/span>鑳墮粡鍓?/span>鍙樺緱鏋佷負(fù)榪垏銆備紶緇熺殑瑙ｅ喅鏂規(guī)閫氳繃鍖栧鍒昏殌銆佺瓑紱誨瓙浣撳拰紱誨瓙鏉熺瓑澶勭悊鏉ュ鍔犺〃闈㈡瀬鎬э紝浠庤屽墛寮卞叾琛ㄩ潰鍖栧鎯版э紝浠ユ鏉ュ寮?/span>綺樻帴鎬ц兘銆傜劧鑰岋紝瀹為檯鎿嶄綔涓線寰浼?/span>澧炲姞鍒跺鐨勫鏉傛у拰涓嶅彲閬垮厤鍦板甫鏉?/span>鐜姹℃煋銆傚洜姝わ紝濡備綍涓嶉氳繃琛ㄩ潰澶勭悊灝卞彲鑾峰緱杈冨己鐨?/span>綺樻帴鎬ц兘渚濈劧鏄伐涓氱晫鍜屽鐣?/span>浜熼渶瑙ｅ喅鐨?/span>閲嶅ぇ闅鵑涔嬩竴銆?/span>
閴翠簬姝わ紝棣?/span>娓腑鏂囧ぇ瀛︼紙娣卞湷錛夋湵涓栧鉤鍜屽紶紲?/span>鍥㈤槦鎻愬嚭閫氳繃灝?/span>鈥滅瀛?span style="font-family:;">-鍋舵瀬鈥濅綔鐢ㄥ紩鍏ヨ兌榛忓墏璁捐錛岃祴浜堝叾瀵逛綆琛ㄩ潰鑳芥潗鏂欑殑楂樺己綺樻帴錛岃緝濂藉湴瑙ｅ喅浜?jiǎn)涓姌q伴毦棰樸?/span>璇ョ爺絀舵垚鏋滀互鈥?/span>Adhering low surface energy materials without surface pre-treatment via ion-dipole interactions鈥?/span>榪戞湡鍙戣〃鍦?/span>ACS Applied Material & Interfaces (doi: 10.1021/acsami.1c11822)錛?/span>棣欐腐涓枃澶у錛堟繁鍦籌級(jí)鐞嗗伐瀛﹂櫌榛勫竻甯?/span>鍗氬＋涓鴻鏂囩涓浣滆咃紝閫氳浣滆呬負(fù)棣欐腐涓枃澶у錛堟繁鍦籌級(jí)鐞嗗伐瀛﹂櫌鏈變笘騫?/span>鏁欐巿鍜屽姪鐞嗘暀鎺?/span>寮犵ズ鍗氬＋銆?/span>
璇ヨ棰樼粍璁捐鍚堟垚鐨勮兌榛忓墏涓?/span>涓縐?/span>鐢?/span>鍚盁鍏辮仛鐗╋紙PHFBA-co-MMA錛夊拰鐤忔按鎬х瀛愭恫浣擄紙EMImTFSI錛?/span>緇?/span>鎴愮殑紱誨瓙鍑濊兌銆?/span>濡傚浘1鎵紺?/span>DFT璁＄畻緇撴灉鍙互鍙戠幇錛屽熀浜?/span>-CF3鍋舵瀬鍜?/span>EMIm闃崇瀛愮殑鈥?/span>紱誨瓙-鍋舵瀬鈥?/span>鐩鎬簰浣滅敤錛屼嬌鑳墮粡鍓?/span>鍙互涓庡師鏈儼鎬х殑鑱氬洓姘熶箼鐑〃闈?/span>浜х敓杈冨己鐨勭粨鍚堣兘錛?/span>12.0 kcal/mol錛夈傚悓鏃剁敱浜庡嚌鑳舵湰浣?/span>鏉愭枡涓?/span>鈥?/span>紱誨瓙-鍋舵瀬鈥?/span>鐩鎬簰浣滅敤鐨勫姩鎬佷氦鎹紝浣垮緱鍒嗙鍩烘潗鐨勫姏寰楀埌鍧囧寑鑰楁暎錛屼粠鑰屽彲浠ラ伩鍏嶈兌綺樺墏鏈韓鐢變簬搴斿姏闆嗕腑瀵艱嚧鑴辯矘銆?/span>榪涗竴姝ラ?/span>榪囦紭鍖栧嚌鑳舵湰韜殑鍐呰仛鍜岃〃闈㈢矘闄勬ц兘錛?/span>鐮旂┒鍥㈤槦鍦?/span>琛ㄩ潰鑳藉彧鏈?/span>19 mJ/m2 鐨勮仛鍥涙盁涔欑儻涓婅幏寰?/span>1.01 MPa鐨勮兌綺?/span>寮哄害錛?/span>鍥?/span>2錛?/span>銆備笉浠呭姝わ紝璇?/span>鑳剁矘鍓傚湪涓嶅悓鍩烘潗錛堣仛涓欑儻銆?/span>鑱氫箼鐑?/span>銆?/span>鑱氭隘涔欑儻銆?/span>鐜葷拑銆?/span>闄剁摲銆?/span>閽㈤搧絳?/span>錛夎〃闈?/span>鍧?/span>灞曠幇鍑?/span>浼樺紓鐨?/span>綺樻帴鎬ц兘銆備笌涓嶅悓綾誨瀷鐨?/span>鍟嗕笟鍖栬兌榛忓墏瀵規(guī)瘮錛?/span>璇ヨ兌榛忓墏鏈夊嚑鍊嶈嚦鍗佸嚑鍊嶇殑鎬ц兘鎻愬崌錛?/span>鍥?/span>3錛夈?/span>璇?/span>鐮旂┒涓?/span>綺樻帴浣庤〃闈㈣兘鏉愭枡鎻愪緵浜?/span>鏂版濊礬錛屽茍涓哄紑鍙戝彲鍟嗕笟鍖栫殑鐗圭鑳墮粡鍓傚甫鏉ュ惎鍙?/span>銆?/span>
鍥?/span>1.錛?/span>a錛?/span>鑳墮粡鍓傜殑綺?/span>鎺ュ師鐞嗭紱錛?/span>b錛?/span>鑳墮粡鍓傛墍鐢ㄥ寲瀛﹁嵂鍝佺粨鏋勫紡錛涳紙c錛?/span>EMImTFSI鍜?/span>HFBA涓?/span>PTFE琛ㄩ潰鐨勭粨鍚堣兘銆傦紙d錛?/span>HFBA涓?/span>EMImTFSI涔嬮棿鐨勫唴鑱氳兘銆?/span>
鍥?/span>2. 閫氳繃浼樺寲EMImTFSI鍜?/span>MMA鐨勯噸閲忓垎鏁幫紝鑾峰緱鏈浣抽煣鎬у拰鏈寮虹矘鎺ュ己搴︾殑鑳墮粡鍓?/span>銆?/span>
鍥?/span>3.錛?/span>a錛?/span>綺樻帴鎬ц兘涓庣瀛愭恫浣撶殑娑︽箍鎬у叿鏈夊瘑鍒囧叧緋伙紱錛?/span>b錛夊拰錛?/span>c錛変負(fù)紱誨瓙鍑濊兌鑳墮粡鍓?/span>涓庡晢涓?/span>鑳墮粡鍓?/span>鐨勬ц兘瀵規(guī)瘮錛涳紙d錛夊湪涓嶅悓鍩烘潗涓婄殑瀹忚綺樻帴鎬ц兘灞曠ず銆?/span>
鐩稿叧閾炬帴
https://doi.org/10.1021/acsami.1c11822